Like I said, I replaced the headgasket in my MGF by following advice I found on the internet. Spend a few days researching before you even think about it, some good videos on youtube.
Opinion seems to vary on whether you should go for an MLS or Elastomer type. From what I've read the elastomer is more forgiving of any imperfections in the head or the liner heights and should be good for up to 70,000 miles, if you are thinking of using an MLS type you need to have the head off and checked before going that way so the car will be off the road for a few more days. Check out the threads in the MG/Rover.org site as well as here, many people over there say don't skim the head unless it needs it.
While you're at it (unless you know for a fact it was very recently done) replace timing belt, tensioner, water pump and alternator belt, you'll have the belts off anyway.
Some say use new head bolts, others say unless the originals are out of tolerence use them as they will be stronger and less likely to break. I think so long as you source your parts from a reliable supplier (not some fly by night ebay cowboy) the bolts supplied should be fine.
It is very much do-able by a home mechanic over a weekend if you have a good selection of tools such as.
Hex 1/2 inch socket set
Bahco S240 Socket Set Square Drive 24 Piece 1/2 in Drive 24pc | eBay This is brilliant for the money if a little short on accessories.
Hex 1/4 inch socket set The Halfords Advanced one is pretty good but the ratchet lets it down.
Halfords | Halfords Advanced Professional 27 Piece Metric Socket Set 1/4" This one is brilliant but a bit short on accessories too.
Bahco SL25 Piece 1/4in Drive Metric Socket / Bit Set with Ratchet & Case | eBay DON'T even think of starting the job without one or both of these sets.
Impact driver to get the crank shaft bolt out without stressing the head, gearbox etc
CLARKE CEW1000 watts ELECTRIC 1/2" IMPACT WRENCH 240 Volts CARRY CASE 6480300 | eBay Not brilliant and not strictly necessary but does the job.
A good torque wrench. I bought a cheap £30 ish draper one and regret it.
Cam pulley locking tool
http://www.ebay.co.uk/itm/Rover-MG-...493?pt=LH_DefaultDomain_3&hash=item2a40ec8f85
I think you also need a 1/2" torq socket set for the head bolts but don't quote me on that.
A good straight edge
A breaker bar
When I did mine I took a risk and pre ordered an MLS kit before checking the head and didn't get it skimmed. One year and several thousand miles later I think I got away with it, like you I had no over heating. If I were doing it again on the Freelander I think I would order a Payne Elastomer kit and do the same again but as I said opinions differ.