I really don't think it'd your ODBII socket. Never ever heard of that, and you said yourself it's only just been scanned. When you get your multimeter out, remember the Range Rover isn't ODBII compliant so don't necessarily expect to see signals where you would on an ODBII compliant car.
I know the timing isn't right, but a Nanocom is the same price as a Tow home (£345) and you'll definitely need it in the future...you might want to consider it. It'll be invaluable for your future ownership.
Lastly, make sure your battery is tip top charged before you start. Crappy batteries are the bane of Range Rovers, and it might be that the battery voltage is too low to allow the re-sync in the first place.
Let us know how you get on, you could be helping someone in the future.