One other thing after she had been running for about 20 mins there was a bit of pressure in the top hose from the rad released the pressure and none since
Sounds like an air-lock, with the engine warm, the rad hoses should be 'hard' ( up to pressure) try running the engine with the rad-cap off for half-hour, blipping it now & again, top up with coolant whilst its running, any air in the system will be pumped around & expelled via the open header tank, we used to 'do' this years ago on large truck diesels, no need to bleed the system, it does it itself!!
As for the hot-side, cold-side heater pipes, i'm not sure on the RR, but is there a water-valve somewhere to control the temp? If so, could it be stuck closed or not working?
Alternatively, an air-lock in the heater matrix, would prevent through flow, see above!!
On some engines I've rebuilt, then filling to the top, rev the thing up high for a few seconds, the coolant completely 'disapears' into the galleries, after which I could get many more litres in.
Of course coolant-loss can be external or internal leaks (head-gasket, water pump etc.) or even a weak pressure relief valve spring on the rad-cap, try a replacement cap, it may be that simple!