Half day? You'll have the head off a 300tdi in about 60 minutes! My record is 40 minutes.
Another hour to clean it all up and check things properly, if you are content it is just a blown gasket and there are clear signs of failure and want to simply refit the head with a new gasket then fine - maybe 2 to 3hrs to put it back together, torque it all properly, refill coolant etc.
I would almost certainly do a bit more than just the HG on it unless I'd done work to it previously or it was clearly good and passed the kero test etc. It would be wise to consider checking valves, lap them in - check valve guides (particularly exhaust) consider a pressure test in case the head is cracked which then caused the HG to go.
This job is not "difficult" but that assumes you have mechanical skills and the right tools - so yes it is difficult if you're not mechanically minded, or a walk in the park if your a time served motor engineer!
The first time I ever did a HG I was a teen, after a few weeks it leaked, I was redoing it again a month later! I learnt so much from making some mistakes that I will never forget these things - I didn't even really bodge or bash anything, I did it well, but I did a couple of daft little things than can be easily forgiven and it just didn't work, my mechanical mentor put it down to the learning process. Ever since then I have always had a thou skim put on a head just so I know it is dead flat and perfectly clean, I always use good gaskets, often new bolts etc.