I don't often disagree with you, But you are wrong.
If you put the cap on at zero pressure , the only way pressure can build up is because of expansion and heat. Your coolant level will rise slightly (if you look at the expansion tank when hot) but the air pressure in the air space will also be higher.
How is that when the system started at zero?
So when its back to cold why shouldn't things go back to the way they were, I.E zero pressure and same coolant level?
The pressure cap rating is to allow excess pressure beyond the system design to relieve pressure, I.E head gasket problem, blocked rad etc. This should not happen under normal conditions.
J