As
@kermit_rr indicates, it's complicated.
Just adding a second battery won't increase the vehicles ability in turning the engine over and winching unless the original battery wasn't big enough in the first place.
You need around 200Amps to start the engine, so your battery needs to have a CCA rating of greater than that so that it will start on a cold day.
The C rating of a battery in Amp Hours defines the amount of power (amps) the battery can deliver in X hours. A C20 rating of 100AH means the battery can supply 5 Amps for 20 hours or 1 amp for 100 Hours.
To start the engine then with a C20 100AH battery you have (theoretically) 30 mins of run time. In reality it will be a lot shorter than that as, as the battery loses voltage the currect rises.
Obviously your engine starts within a few seconds (or it should) so you are OK with a lower capacity battery as long as it can provide the required CCA. I believe that LR specify a 70AH 570CCA battery.
Your winch will work fine too as long as the battery provides enough power for as long as you want to run the winch.
If you have 2 identical batteries wired in parrallel (+ to + and - to -) then the CCA and the AH will sum so 2 x 100AH 600CCA batteries will become 1 x 200AH 1200CCA, however matching batteries of that capacity is very difficult and if they are different then things start to go wrong. Connecting them together will be tricky too.
You would be better to fit a 120AH 900CCA battery (or larger if it will fit in your battery box) and uprate your alternator to 100A and run the engine if you need to winch for anymore than 15 mins.
I you do feel the urge to install a 'secondary' or leisure battery (ie one that isn't used for staring the engine etc) then there are loads of systems out there that will allow you to attach long duration, low current applications (like a radio, internal lights, fridge etc) and charge each battery independantly without causing any damage to either. These twin charge systems allow you to fit different types of batteries without any damage or risk of losing power from your primary battery so you can always start the engine and spin up the alternator.
My winch draws around 150Amps when its pulling near capacity, so a similar load to starting the engine, in fact it's greater as the engine starts within seconds and the winch maybe pulling for 10's of minutes.
Once i'm set up and need to pull a load with the winch, I always start the engine.