The M62TUB is not a straight forward engine to refurbish the crankcase on as the bores are coated and generally not able to be rehoned and can possibly be recoated and i have heard of liners being fitted but generally from what i can tell a dead crankcase is swapped for a not so dead crankcase or complete second hand engine.
Turners don't touch the M62 engine when i last checked, they refurbish the P38 derivative of the Rover 3.5 V8 in its 4.0 or 4.6 guise.
Heads / lifters / valves are fairly conventional but apart from a head gasket going due to overheating i haven't read of many problems, apart from a noisy lifter.
if your compression is good then i would concentrate on the things that will kill the engine potentially like the PCV Valve and relevant pipework and the timing chain guides breaking down and allowing the timing chain to jump a tooth or several killing the engine.
The 80 degree modification is an easy good idea but most of the damage caused by running at 105 degrees instead of 80-90 will have already caused the plastic timing chain and cam chain guides to become brittle so you don't get much warning if any before they shatter and it is my belief that LPG engines are more vulnerable than non LPG.
if you are ok with the spanners and have the time and money the timing chain and cam chain guides are ok to do, the pcv valve is frustrating but again not horrendous.
You probably have leaking cam cover seals and possibly front timing chain cover seals which probably would have been done by now as again they turn to brittle plastic and start to leak.
The ZF transmission has probably already been done by your mileage and as long as the valve block was good and the torque converter replaced or refurbished then should be ok and the timing chain guides are probably not far away.
Bit of info here.
http://bmwv8capri.yolasite.com/tuning-the-m60-m62.php
http://www.meeknet.co.uk/e38/
As already mentioned you will have plenty of other issues to spend your money on but the engine would be the one thing that would make the RR uneconomical to repair or very painful to replace.
You may find that by the time it has reached 140K some other poor bastard has replaced most of the problem parts already