I would be using something a bit heavier than that - the whole "installation" must be capable of withstanding a cold crank startup, which may also be prolonged in the event of other engine difficulties - you don't want anything to cook - the standard landrover cable gets warm after a lot of cranking, so anything less than this really is a big nono.
The switch is rated at 150amps, which means that it has been designed to allow 150amps through it without any problems, if you were to isolate the supply it would be just fine, but when you connect it up and start trying to draw lots of current through it you will run into issues.