the rover head is really bad for flow - a decent set of heads should liberate ~25-30hp
a decent cam will make the engine rev better.
what you can do is swap your crank and rods for 4.6 items and keep the 4.0l pistons for a high comp ratio 4.6.
3.9 will fit 3.5 ,its somethng that was done a lot as well as fiting h/c pistons in defenders etcSorry to hijack but;
Will a 3.9 performance cam fit ? Got my eye on one
Also looking into an electric dizzy purely for water when offroading or during the floods here but that might help too ?